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Mechanical and tribological behavior of silicon nitride and silicon carbon nitride coatings for total joint replacements

机译:用于全接头置换的氮化硅和氮化硅碳涂层的机械和摩擦学行为

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摘要

Total joint replacements currently have relatively high success rates at 10–15 years; however, increasing ageing and an active population places higher demands on the longevity of the implants. A wear resistant configuration with wear particles that resorb in vivo can potentially increase the lifetime of an implant. In this study, silicon nitride (SixNy) and silicon carbon nitride (SixCyNz) coatings were produced for this purpose using reactive high power impulse magnetron sputtering (HiPIMS). The coatings are intended for hard bearing surfaces on implants. Hardness and elastic modulus of the coatings were evaluated by nanoindentation, cohesive, and adhesive properties were assessed by micro-scratching and the tribological performance was investigated in a ball-on-disc setup run in a serum solution. The majority of the SixNy coatings showed a hardness close to that of sintered silicon nitride (∼18 GPa), and an elastic modulus close to that of cobalt chromium (∼200 GPa). Furthermore, all except one of the SixNy coatings offered a wear resistance similar to that of bulk silicon nitride and significantly higher than that of cobalt chromium. In contrast, the SixCyNz coatings did not show as high level of wear resistance.
机译:目前,全关节置换术在10至15年内具有较高的成功率。但是,随着年龄的增长和活动人口的增加,对植入物的寿命提出了更高的要求。具有在体内吸收的磨损颗粒的耐磨构造可以潜在地增加植入物的寿命。在这项研究中,为此使用反应性高功率脉冲磁控溅射(HiPIMS)生产了氮化硅(SixNy)和碳氮化硅(SixCyNz)涂层。该涂层用于植入物上的坚硬支承表面。通过纳米压痕评估涂层的硬度和弹性模量,内聚性,并通过微划痕评估粘合性能,并在血清溶液中通过圆盘安装实验研究摩擦性能。大多数SixNy涂层的硬度接近于烧结氮化硅(〜18 GPa),弹性模量接近钴铬(〜200 GPa)。此外,除SixNy涂层之一外,所有涂层均具有与块状氮化硅相似的耐磨性,并且显着高于钴铬的耐磨性。相反,SixCyNz涂层的耐磨性不高。

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